YbB12 has been investigated energetically as a typical Kondo insulator. To study detailed formation mechanism of Kondo energy gap, we have investigated transport and magnetic properties of Yb1-xR3+xB12 (R3+ = non-magnetic trivalent ions). Recently, we have recently succeeded in substitution of Ca2+ for Yb site in YbB12 by high-pressure synthesis. In Ca- and Lu-substituted alloys both of magnetic susceptibility and specific heat C/T at low temperatures, remarkably show larger increase than those of powdered YbB12. These increases are due to giant increase of density of state in an in-gap state.
