HYDROGENOTUNGSTATO COMPLEXES WITH TIN HALOGENURES (IV): INFRARED AND MÖSSBAUER STUDIES

Abstract

Six new hydrogenotungstato adducts and complexes have been synthesized and studied by infrared and Mössbauer techniques. The structures are mainly discrete, the anion behaving as a bidentate -one case- or a monodentate ligand in most cases. When extra hydrogen bonds are considered, supramolecular architectures may be obtained.

Keywords

• discrete structures, hydrogenotungstato tin (IV) halides adducts, infrared, monodentate hydrogenotungstate ligand, Mössbauer, supramolecular architectures