Acta Crystallographica Section E (Dec 2010)

Diethyl 2-amino-5-[(E)-(1-methyl-1H-pyrrol-2-yl)methylideneamino]thiophene-3,4-dicarboxylate

  • Stéphane Dufresne,
  • W. G. Skene

DOI
https://doi.org/10.1107/S1600536810046775
Journal volume & issue
Vol. 66, no. 12
pp. o3221 – o3221

Abstract

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The structure of the title compound, C16H19N3O4S, shows the planes described by the thiophene and the pyrroles are twisted by 17.06 (4)°. Additionally, the structure shows the azomethine bond adopts the E configuration, while the pyrrole is disordered as a heterocycle flip [occupancy ratio 0.729 (5):0.271 (5)]. The three-dimensional network is well packed and involves N–H...O hydrogen bonding and π–π stacking [centroid–centroid distance = 4.294 (8) Å].