Nano-Micro Letters (Apr 2023)
Efficient Semi-Transparent Wide-Bandgap Perovskite Solar Cells Enabled by Pure-Chloride 2D-Perovskite Passivation
- Liu Yang,
- Yongbin Jin,
- Zheng Fang,
- Jinyan Zhang,
- Ziang Nan,
- Lingfang Zheng,
- Huihu Zhuang,
- Qinghua Zeng,
- Kaikai Liu,
- Bingru Deng,
- Huiping Feng,
- Yujie Luo,
- Chengbo Tian,
- Changcai Cui,
- Liqiang Xie,
- Xipeng Xu,
- Zhanhua Wei
Affiliations
- Liu Yang
- Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University
- Yongbin Jin
- Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University
- Zheng Fang
- MOE Engineering Research Center for Brittle Materials Machining, Institute of Manufacturing Engineering, College of Mechanical Engineering and Automation, Huaqiao University
- Jinyan Zhang
- Gold Stone (Fujian) Energy Company Limited
- Ziang Nan
- Collaborative Innovation Center of Chemistry for Energy Materials, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University
- Lingfang Zheng
- Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University
- Huihu Zhuang
- Gold Stone (Fujian) Energy Company Limited
- Qinghua Zeng
- Gold Stone (Fujian) Energy Company Limited
- Kaikai Liu
- Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University
- Bingru Deng
- Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University
- Huiping Feng
- Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University
- Yujie Luo
- Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University
- Chengbo Tian
- Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University
- Changcai Cui
- MOE Engineering Research Center for Brittle Materials Machining, Institute of Manufacturing Engineering, College of Mechanical Engineering and Automation, Huaqiao University
- Liqiang Xie
- Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University
- Xipeng Xu
- MOE Engineering Research Center for Brittle Materials Machining, Institute of Manufacturing Engineering, College of Mechanical Engineering and Automation, Huaqiao University
- Zhanhua Wei
- Xiamen Key Laboratory of Optoelectronic Materials and Advanced Manufacturing, Institute of Luminescent Materials and Information Displays, College of Materials Science and Engineering, Huaqiao University
- DOI
- https://doi.org/10.1007/s40820-023-01090-w
- Journal volume & issue
-
Vol. 15,
no. 1
pp. 1 – 14
Abstract
Highlights Three bulky cation chlorides (PMACl, PEACl and NMACl) are used to modify the perovskite surface and form pure-anion 2D (PMA)2PbCl4, mixed-anion 2D (PEA)2Pb(I x Cl4-x ), and non-2D NMAI passivation layers, respectively. Intermolecular interactions between the bulky cations and the strength of cation-halide hydrogen bonds are critical to forming the three distinct passivation layers. Semi-transparent wide-bandgap perovskite solar cells (WBG-PSCs) with ITO as the back electrode show hysteresis-free PCE of 18.60% and V OC deficit of 0.49 V.
Keywords
