Membranes Based on PTMSP/PVTMS Blends for Membrane Contactor Applications

Abstract

In this work, perspective polymeric materials were developed for membrane contactor applications, e.g., for the dissolved oxygen removal from amine CO2 capture solvents. Several polymeric blends based on poly[1-trimethylsilyl-1-propyne] (PTMSP) and poly[vinyltrimethylsilane] (PVTMS) were studied. The gas and water vapor sorption and permeability coefficients for the PTMSP/PVTMS blend membranes at different PVTMS contents (0–100%) were obtained under temperatures of 30 and 60 °C for the first time. As the PVTMS content increases, the O2 and CO2 permeabilities decrease by 160 and 195 times at 30 °C, respectively. The fractional accessible volume of the polymer blends decreases accordingly. The transport of the CO2 capture solvent vapors through the PTMSP/PVTMS blend membranes were determined in thermo-pervaporation (TPV) mode using aqueous monoethanolamine (30%), N-methyldiethanolamine (40%), and 2-amino-2-methyl-1-propanol (30%) solutions as model amine solvents at 60 °C. The membranes demonstrated high pervaporation separation factors with respect to water, resulting in low amine losses. A joint analysis of the gas permeabilities and aqueous alkanolamine TPV data allowed us to conclude that the polymer blend composition of PTMSP/PVTMS 70/30 provides an optimal combination of a sufficiently high oxygen permeability and the pervaporation separation factor at a temperature of 60 °C.

Keywords

• carbon dioxide
• membrane contactor
• PTMSP
• PVTMS
• oxygen removal