Journal of Materials Research and Technology (Jul 2017)

Modification of cyanate resin by conjugated tri-component interpenetrating polymer networks

  • Wang Chuang,
  • Jiao Geng-sheng,
  • Zhu Bao-lin,
  • Peng Lei,
  • He Wen-min,
  • Zhao Li-ping

DOI
https://doi.org/10.1016/j.jmrt.2016.12.002
Journal volume & issue
Vol. 6, no. 3
pp. 226 – 231

Abstract

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Cyanate ester (CE) resin was modified in a multi-component way using the technology of conjugated tri-component interpenetrating polymer networks (CTC-IPN). Experimental results showed that the three components in the modified composite existed undependably and they interweaved irregularly in the structure of IPN to form a unique supermolecule structure. The analysis by differential scanning calorimetry (DSC) indicated that the Tg of the modified CE was increased by 22 °C, compared with the Tg prior to modification. When the amount of an initiator was 0.3% or 0.4% and concurrently the ratio of PST/PMMA/CE was 15/15/85, the flexural strength and the impact strength reached the maximum values. Compared with those of pure CE, the flexural strength was increased by 22.65% and the impact strength by 94.99%, respectively.

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