Marker Method in Studying the Defect Structure in Products of the Oxidation of Highly Disordered Substrates

Grzesik Z.; Poczekajlo A.; Smola G.; Mrowec S.

doi:10.1515/htmp-2014-0152

High Temperature Materials and Processes (Jan 2016)

Marker Method in Studying the Defect Structure in Products of the Oxidation of Highly Disordered Substrates

Grzesik Z.,
Poczekajlo A.,
Smola G.,
Mrowec S.

Affiliations

Grzesik Z.: Faculty of Materials Science and Ceramics, Department of Physical Chemistry and Modelling, AGH University of Science and Technology, al. A. Mickiewicza 30, 30–059 Krakow, Poland
Poczekajlo A.: Faculty of Materials Science and Ceramics, Department of Physical Chemistry and Modelling, AGH University of Science and Technology, al. A. Mickiewicza 30, 30–059 Krakow, Poland
Smola G.: Faculty of Materials Science and Ceramics, Department of Physical Chemistry and Modelling, AGH University of Science and Technology, al. A. Mickiewicza 30, 30–059 Krakow, Poland
Mrowec S.: Faculty of Materials Science and Ceramics, Department of Physical Chemistry and Modelling, AGH University of Science and Technology, al. A. Mickiewicza 30, 30–059 Krakow, Poland

DOI: https://doi.org/10.1515/htmp-2014-0152
Journal volume & issue: Vol. 35, no. 1
pp. 21 – 28

Abstract

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The interpretation of marker experiments in studying the formation mechanism and defect structure of higher oxides during oxidation of lower oxides, showing rather high deviations from stoichiometry, has been discussed. It has been shown that correct results can be obtained only if the concentration of point defects in the substrate is taken into account. Theoretical considerations presented in this paper have been illustrated by the experimental results obtained during sulphidation of highly disordered Co1-yS to form CoS2, as well as Ni1-yS to form NiS2.

Published in High Temperature Materials and Processes

ISSN: 0334-6455 (Print); 2191-0324 (Online)
Publisher: De Gruyter
Country of publisher: Poland
LCC subjects: Technology: Chemical technology: Chemicals: Manufacture, use, etc.
Website: https://www.degruyter.com/view/journals/htmp/htmp-overview.xml

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