A Surprisingly High Enhancing Potential of Nitric Acid in Sulfuric Acid–Methylamine Nucleation
Fukang Qiao,
Rongjie Zhang,
Qiaojing Zhao,
Fangfang Ma,
Jingwen Chen,
Hong-Bin Xie
Affiliations
Fukang Qiao
Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China
Rongjie Zhang
Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China
Qiaojing Zhao
Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China
Fangfang Ma
Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China
Jingwen Chen
Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China
Hong-Bin Xie
Key Laboratory of Industrial Ecology and Environmental Engineering (Ministry of Education), School of Environmental Science and Technology, Dalian University of Technology, Dalian 116024, China
Nitric acid (NA) has recently been found to enhance sulfuric acid (SA)-driven new particle formation (NPF) at low temperatures (≤240 K). However, studies on the role of NA in atmospheric NPF remain limited. Herein, we explored the enhancement effect of NA on binary SA–methylamine (MA) nucleation by investigating the mechanism and kinetics of (NA)x(SA)y(MA)z (0 ≤ x, 0 ≤ y, x + y ≤ 3, 0 ≤ z ≤ 3) clusters using quantum chemical calculations and cluster dynamics simulations. We found that the mixed ternary NA-SA-MA clusters have lower evaporation rates compared to the corresponding NA-SA–dimethylamine (DMA) and NA-SA–ammonia (A) clusters, indicating the stronger binding ability of NA with respect to SA-MA clusters. At atmospheric conditions (T ≥ 278.15 K), NA can enhance the cluster formation rate of SA-MA by about six orders of magnitude, demonstrating a surprisingly high enhancing potential. Moreover, NA acts as an important participant in the cluster growth pathways of the NA-SA-MA system, as opposed to the “bridging” role of NA in the previously studied NA-SA-A system. This study proposes the first case of NA efficiently enhancing SA–amine nucleation at ambient temperature, suggesting a larger impact of NA in atmospheric NPF than previously expected.
