Molecules (Oct 2023)
Fabricating BiOCl Nanoflake/FeOCl Nanospindle Heterostructures for Efficient Visible-Light Photocatalysis
Abstract
Fabricating heterostructures with abundant interfaces and delicate nanoarchitectures is an attractive approach for optimizing photocatalysts. Herein, we report the facile synthesis of BiOCl nanoflake/FeOCl nanospindle heterostructures through a solution chemistry method at room temperature. Characterizations, including XRD, SEM, TEM, EDS, and XPS, were employed to investigate the synthesized materials. The results demonstrate that the in situ reaction between the Bi precursors and the surface Cl− of FeOCl enabled the bounded nucleation and growth of BiOCl on the surface of FeOCl nanospindles. Stable interfacial structures were established between BiOCl nanoflakes and FeOCl nanospindles using Cl− as the bridge. Regulating the Bi-to-Fe ratios allowed for the optimization of the BiOCl/FeOCl interface, thereby facilitating the separation of photogenerated carriers and accelerating the photocatalytic degradation of RhB. The BiOCl/FeOCl heterostructures with an optimal composition of 15% BiOCl exhibited ~90 times higher visible-light photocatalytic activity than FeOCl. Based on an analysis of the band structures and reactive oxygen species, we propose an S-scheme mechanism to elucidate the significantly enhanced photocatalytic performance observed in the BiOCl/FeOCl heterostructures.
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