Engineering Band Structure of SnO₂ Nanoparticles via Coupling with g-C₃N₄ Nanosheet for the Detection of Ethanolamine

Abstract

Volatile organoamines are important industrial raw materials and chemicals. Long-term exposure to amines could be harmful to human health and even cause serious pollution. In this study, SnO2 decorated g-C3N4 material was fabricated and used as a sensor material for the detection of ethanolamine (EA). The structures, morphology, surface chemical states, and band structure were characterized, and gas sensing was studied. The results showed that SnO2 nanoparticles were dispersed on g-C3N4, and band structure was dependent on g-C3N4 doping. Notably, the interface heterojunction was conducive to electron transferring and O2 molecule adsorption; the formed reactive oxygen species enhanced the reaction between oxygen and EA, thus leading to high sensitivity to EA. This composite exhibited a high response that was 2.6 times higher than that of pure SnO2, and the detection limit reached 294 ppb. A g-C3N4/SnO2-based sensor displayed a high selectivity to EA with a fast response time (1 s) and recovery time (20 s) at low operating temperatures. In particular, this sensor exhibited a linear relationship between the response and concentration, which is required for quantitative analysis.

Keywords

• g-C₃N₄/SnO₂
• heterojunction
• band structure
• ethanolamine
• sensors