A photocatalytic and electrochemical study of gold nanoparticles synthesized by a green approach

Abstract

Quasi-spherical gold nanoparticles mixed with a controlled amount of gold nano triangles were obtained through a green chemical method using leaf extract of Loeselia mexicana . Moreover, the influence of the extract and HAuCl _4 solution concentration in the morphology of the nanoparticles was studied. The nanoparticle preparation was performed by varying the concentration of the extract and precursor salt. The catalytic activity of the as-prepared nanoparticles was studied by the reduction of methylene blue, rhodamine B, and gentian violet organic dyes. Also, cyclic voltammetry profiles were obtained in order to analyze the electrochemical response of the nanoparticles. The morphology and structural characterization were analyzed by UV–vis, SEM, TEM, FTIR, and XRD. The SEM analysis reveals gold nanoparticles with spherical and triangular morphologies. The UV–vis spectra revealed that the extract concentration influenced the morphology and amount of the obtained gold nanoparticles. The XRD and TEM analysis showed that gold nanoparticles presented a face-centered cubic lattice structure. The cyclic voltammetry analysis confirms a high-sensitivity electrochemical response and stability corresponding to the gold nano triangles. Finally, the presence of gold nano triangles shapes influenced the efficiency of the degradation of the dyes due to their high specific surface area.

Keywords

• green synthesis
• gold nanoparticles
• gold nanotriangles
• catalytic activity
• electrochemistry
• structural characterization