Acta Crystallographica Section E (Jul 2010)

9-Benzyl-10-methylacridinium trifluoromethanesulfonate

  • Damian Trzybiński,
  • Beata Zadykowicz,
  • Karol Krzymiński,
  • Artur Sikorski,
  • Jerzy Błażejowski

DOI
https://doi.org/10.1107/S160053681001963X
Journal volume & issue
Vol. 66, no. 7
pp. o1548 – o1549

Abstract

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In the crystal structure of the title compound, C21H18N+·CF3OS3−, the cations form inversion dimers through π–π interactions between the acridine ring systems. These dimers are further linked by C—H...π interactions. The cations and anions are connected by C—H...O, C—F...π and S—O...π interactions. The acridine and benzene ring systems are oriented at a dihedral angle of 76.8 (1)°with respect to each other. The acridine moieties are either parallel or inclined at an angle of 62.4 (1)° in the crystal structure.