CHIMIA (Apr 2010)

Understanding Selective Oxidations

  • Ulrich Neuenschwander,
  • Natascia Turrà,
  • Christof Aellig,
  • Philipp Mania,
  • Ive Hermans

DOI
https://doi.org/10.2533/chimia.2010.225
Journal volume & issue
Vol. 64, no. 4

Abstract

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Functionalizing organic molecules is an important value-creating step throughout the entire chemical value-chain. Oxyfunctionalization of value-chain. Oxyfunctionalization of e.g. C–H or C=C bonds is one of the most important functionalization technologies used industrially. The major challenge in this field is the prevention of side reactions and/or the consecutive over-oxidation of the desired products. Despite its importance, a fundamental understanding of the intrinsic chemistry, and the subsequent design of a tailored engineering environment, is often missing. Industrial oxidation processes are indeed to a large extent based on empirical know-how. In this mini-review, we summarize some of our previous work to help to bridge this knowledge gap and elaborate on our ongoing research.

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