Study on the pore evolution of Xinjiang oil shale under pyrolysis based on joint characterization of LNTA and MIP

Abstract

Abstract During the in-situ exploitation of oil shale, the evolution of pore structure will affect the heat transfer medium and the transport capacity of products. In this study, using the oil shale from Jimsar region of Xinjiang, in combination with the low-temperature nitrogen adsorption experiment (LNTA) and high-pressure mercury injection experiment (MIP), the effect of temperature on evolution law of its pores during pyrolysis were analyzed according to the LNTA and MIP joint characterization results. The results show as follows: the change curve of oil shale porosity with pyrolysis final temperature in Xinjiang shows an “S” shape. The pore volume increases slightly before 300 °C, and it shows an increasing trend in the subsequent temperature range, with the mesopore volume change being the most noticeable. However, the increase slows down after 600 °C. The evolution of full-scale pores in the pyrolysis process of oil shale is reflected by the joint characterization of LNTA and MIP, which indicates that the temperature has a controlling effect on the evolution of pore, and provides basic theoretical support for how to improve the oil recovery rate of exploitation of oil shale.

Keywords

• Oil shale
• Nitrogen adsorption
• Mercury injection
• Pore structure
• Joint characterization