In situ single-crystal synchrotron X-ray diffraction studies of biologically active gases in metal-organic frameworks

Abstract

Metal–organic frameworks have demonstrated promise for the storage and release of biologically active gases. Here, an in situ single crystal X-ray diffraction study using synchrotron radiation elucidates the binding mechanisms and geometries of nitric oxide and carbon monoxide gases in activated frameworks Ni-CPO-27 and Co-4,6-dihydroxyisophthalate.