Arabian Journal of Chemistry (Nov 2023)

Studying the kinetic parameters of BaTi5O11 by using the thermoluminescence technique

  • Manar Mostafa,
  • Mohamed F. El-Shahat,
  • Mohamed El-Kinawy,
  • Nabil El-Faramawy,
  • Moritz Riede,
  • Ghada Bassioni

Journal volume & issue
Vol. 16, no. 11
p. 105247

Abstract

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The present study discusses the thermoluminescence (TL) characteristics of monoclinic barium titanate (BaTi5O11) which is chemically prepared using the sol–gel technique. The crystallinity is confirmed by X-ray diffraction, and the oxidation state of each element, morphology, and particle size of the prepared powder are chemically probed by different spectroscopic tools including X-ray Photoelectron Spectroscopy and Energy dispersive X-Ray spectroscopy. The sample is irradiated by a beta (β)-source with different applied doses in the range of 1.1––385 Gy. The kinetic parameters which correspond to the charge carrier traps were determined. The analysis methods indicated that the TL glow curve of BaTi5O11 consists of 6 overlapped peaks corresponding to 6 electron traps. The values for the trap depth are found to be in the range 0.94–1.40 eV and the TL glow peaks are located between 380.4 and 560.5 K. The study confirms the potential of BaTi5O11 for β-dosimetry.

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