Acta Crystallographica Section E: Crystallographic Communications (Jan 2017)

Crystal structure of catena-poly[[bis(N-acethylthiomorpholine-κS)copper(I)]-μ-iodido]

  • Hojae Chiang,
  • Tae Ho Kim,
  • Hyunjin Park,
  • Jineun Kim

DOI
https://doi.org/10.1107/S2056989016019794
Journal volume & issue
Vol. 73, no. 1
pp. 53 – 55

Abstract

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The reaction of copper(I) iodide with N-acetylthiomorpholine (L, C6H11NOS) in acetonitrile results in a coordination polymer with composition [CuI(L)2]n. The CuI atom is coordinated by two S atoms and two I atoms, adopting a distorted tetrahedral environment. The μ2-bridging mode of the I atoms gives rise to chains extending parallel to [010]. C—H...O hydrogen-bonding interactions between the chains lead to a three-dimensional network.

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