Geosciences (Dec 2022)
Assessment of Some Clay-Based Products Available on Market and Designed for Topical Use
Abstract
The establishment of quality requirements of clay-based products, for medicinal, wellness, and aesthetic purposes, is mainly sustained by the good interactions between the clay-based formulation and the skin. The release of ionizable elements and their availability to percutaneous absorption should be, ideally, physiologically effective during passive percutaneous absorption. Clay-based products are promoted in the European market as therapeutic clays or aesthetics, which is labeling that combines characteristics of medicinal products along with cosmetics. Different countries regulate these products under different legal frameworks. This study focuses on the mineralogical, chemical, and technological characterization of some clay-based products available on the market, designed for topical use, framed in the peloids concept, and claimed as natural products. The main goals are to contribute to the establishment of clay-based products quality criteria as reliable scientific information, aiming for the compliance of intended use, the information for the potential health hazards and toxicological effects of clay-based products, and the distinction in what concerns therapeutic compliance and aesthetic or wellbeing product certification. There were 13 clayed products for cosmetic purposes, available online and in commercial stores, together with three thermal peloids, that were studied. Mineralogical composition of the 16 studied samples reveals a polymineralic association with the presence of variable quantities of quartz, calcite, and feldspars, whereas clay minerals are not predominant and characterized by the presence of clay-based fraction content, composed mainly by illite, smectite, and kaolinite in variable amounts and with several mineral associations. The clay-based products contain median values of 17 ppm As, 315 ppm Ba, 79 ppm Cr, 11 ppm Co, 29 ppm Pb, 26 ppm Ni, and 62 ppm Zn. One sample presented 4.1 ppm of Cd. The studied samples have safety concerns about specific limits of As, Ba, Cd, Cr, Co, Pb, Ni, and Zn which are above the regulated avoidable limits. Samples’ pH is out of range of skin’s natural pH as well.
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