Acta Crystallographica Section E (Jan 2012)

3a,11b-Dihydroxy-3a,11b-dihydro-1H-imidazo[4,5-f][1,10]phenanthroline-2(3H)-thione

  • Hua Wang,
  • Peng Mei,
  • Wen-Yi Chu,
  • Zhi-Zhong Sun,
  • Yan-Jun Hou

DOI
https://doi.org/10.1107/S1600536811053967
Journal volume & issue
Vol. 68, no. 1
pp. o208 – o208

Abstract

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The title compound, C13H10N4O2S, was prepared through a cyclization reaction of 1,10-phenanthroline-5,6-dione and thiourea. The dihedral angle between the pyridine rings is 8.22 (2)°. In the crystal, molecules are connected by N—H...O, O—H...N, N—H...S and O—H...S hydrogen bonds, forming a three-dimensional network.