Adsorption and inhibition performance of the novel cationic Gemini surfactant as a safe corrosion inhibitor for carbon steel in hydrochloric acid

Abstract

The new synthesized cationic Gemini surfactant (CGS) was tested as a corrosion inhibitor for carbon steel (CS) in 1.0 M hydrochloric acid using weight loss, electrochemical spectroscopy and potentiodynamic polarization. The inhibition efficiency is increased by increasing the CGS concentration and is almost constant within the temperature range studied. The inhibition was explained by adsorption of the CGS molecule on the CS surface. A mixed-type inhibitor is suggested for the inhibitory effects of CGS as revealed by the potentiodynamic polarization technique. The changes in impedance parameters suggested that the adsorption of the inhibitor on the CGS surface led to the formation of protective films. The adsorption of the CGS on the surface of CS obeys Langmuir adsorption isotherm. Thermodynamic and kinetic parameters were calculated and discussed.

Keywords

• Steel
• EIS
• weight loss
• polarization
• acid inhibition
• interfaces