Acta Crystallographica Section E (Sep 2008)

(2S,3S)-3-(4-Chlorophenyl)-8-methyltropane-2-carboxylic acid

  • Jian-Guo Lin,
  • Jie Tang,
  • Xiao-Min Li,
  • Song-Pei Wang,
  • Zheng-Ping Chen

DOI
https://doi.org/10.1107/S1600536808025002
Journal volume & issue
Vol. 64, no. 9
pp. o1732 – o1732

Abstract

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In the title compound, C15H18ClNO2, the internal torsion angles of the tropane ring are comparable to those of tropane rings in the crystal structures reported for cocaine and its derivatives. There is an intramolecular hydrogen bond between the N atom in the tropane ring and the O atom of the carboxyl group. The crystal structure is further stabilized by many weak C—H...O interactions between the molecules in the ab plane, forming a two-dimensional supramolecular network.