Acta Crystallographica Section E (Jul 2011)

(15-Crown-5-κ5O)[S-(E)-1,2-dichlorovinyl thiosulfato-κO]sodium

  • Dong-Qing Sun,
  • Jing-Kui Yang

DOI
https://doi.org/10.1107/S1600536811022252
Journal volume & issue
Vol. 67, no. 7
pp. m934 – m934

Abstract

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In the title complex, [Na(C2HCl2O3S2)(C10H20O5)], there are two independent complex units in the asymmetric unit, one of which has a 55:45% disorder in the 15-crown-5 component. The coordination sphere about the Na atom in each complex unit comprises five bonds to O atoms of the crown ether [Na—O = 2.390 (7)–2.466 (6) Å] and one to a thiosulfate O atom [Na—O = 2.305 (4) and 2.447 (3) Å].