Optical properties for TiO2 / PMMA nanocomposite thin films prepared by plasma jet

Abstract

PMMA/TiO2 homogeneous thin films were deposited by using plasma jet system under normal atmospheric pressure and room temperature. PMMA/TiO2 nanocomposite thin film synthesized by plasma polymerization. Titanium oxide was mixed with Methyl Methacrylate Monomer (MMA) with specific weight ratios (1, 3 and 5 grams of TiO2 per 100 ml of MMA). Optical properties of PMMA/TiO2 nanocomposite thin films were characterized by UV-Visible absorption spectra using a double beam UV-Vis-NIR Spectrophotometer. The thin films surface morphological analysis is carried out by employing SEM. The structure analysis are achieved by X-ray diffraction. UV-Visible absorption spectra shows that the increasing the concentration of titanium oxide added to the polymer leads to shift the peak position (λmax) toward the infrared region of the electromagnetic spectrum. Also the peak width increases when the concentration of TiO2 increases. It can be controlled optical energy band gap of PMMA/TiO2 nanocomposite thin films by changing concentration of TiO2. SEM indicate a uniform distribution of titanium oxide particles in PMMA matrix. The x-ray diffraction pattern indicated that the thin films have amorphous structure.

Keywords

• Optical properties, plasma jet, PMMA/TIO2 nanocomposite, plasma polymerization.