Acta Crystallographica Section E (Nov 2010)

Diaquabis(4-carboxy-2-propyl-1H-imidazole-5-carboxylato-κ2N3,O4)cobalt(II) N,N-dimethylformamide disolvate

  • Shi-Jie Li,
  • Li-Li Ji,
  • Wen-Dong Song,
  • Shi-Wei Hu,
  • Pei-Wen Qin

DOI
https://doi.org/10.1107/S1600536810042054
Journal volume & issue
Vol. 66, no. 11
pp. m1443 – m1444

Abstract

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In the title complex, [Co(C8H9N2O4)2(H2O)2]·2C3H7NO, the CoII cation (site symmetry overline1) is six-coordinated by two 5-carboxy-2-propyl-1H-imidazole-4-carboxylate ligands and two water molecules in a distorted octahedral environment. In the crystal structure, the complex molecules and dimethylformamide solvent molecules are linked by extensive O—H...O and N—H...O hydrogen bonding into sheets lying parallel to (21overline{1}).