Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n

Gopal Ram; Sharma Nikita; Nagar Meena; Chaudhary Archana; Mobin Shaikh M.; Bohra Rakesh

doi:10.1515/mgmc-2018-0004

Main Group Metal Chemistry (May 2018)

Synthesis and characterization of the coordination polymer [(THF)K(μ-OPri)2Al(μ-OPri)2]n

Gopal Ram,
Sharma Nikita,
Nagar Meena,
Chaudhary Archana,
Mobin Shaikh M.,
Bohra Rakesh

Affiliations

Gopal Ram: Department of Chemistry, University of Rajasthan, Jaipur 302004, Rajasthan, India
Sharma Nikita: Department of Chemistry, Government Girls College, Chomu, Jaipur, Rajasthan, India
Nagar Meena: Department of Chemistry, University of Rajasthan, Jaipur 302004, Rajasthan, India
Chaudhary Archana: Discipline of Chemistry, School of Basic Sciences, Indian Institute of Technology Indore, Khandwa Road, Indore 452017, India
Mobin Shaikh M.: Discipline of Chemistry, School of Basic Sciences, Indian Institute of Technology Indore, Khandwa Road, Indore 452017, India
Bohra Rakesh: Department of Chemistry, University of Rajasthan, Jaipur 302004, Rajasthan, India

DOI: https://doi.org/10.1515/mgmc-2018-0004
Journal volume & issue: Vol. 41, no. 1-2
pp. 43 – 46

Abstract

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Reaction of [Al(OPri)3] with K(OPri), in 1:1 molar ratio in refluxing anhydrous tetrahydrofuran yields a polymeric complex [(THF)K(μ-OPri)2Al(μ-OPri)2]n. The complex is characterized by spectroscopic studies and single crystal X-raydiffraction analysis.

Published in Main Group Metal Chemistry

ISSN: 0792-1241 (Print); 2191-0219 (Online)
Publisher: De Gruyter
Country of publisher: Poland
LCC subjects: Science: Chemistry
Website: https://www.degruyter.com/view/j/mgmc

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