Acta Crystallographica Section E (Jan 2011)

16-[(E)-4-Bromobenzylidene]-13-(4-bromophenyl)-2-hydroxy-11-methyl-1,11-diazapentacyclo[12.3.1.02,10.03,8.010,14]octadeca-3(8),4,6-triene-9,15-dione

  • Hoong-Kun Fun,
  • Jia Hao Goh,
  • Subbu Perumal,
  • Hasnah Osman,
  • Raju Suresh Kumar

DOI
https://doi.org/10.1107/S1600536810051585
Journal volume & issue
Vol. 67, no. 1
pp. o137 – o138

Abstract

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In the title pyrrolidine compound, C30H24Br2N2O3, the two fused pyrrolidine rings adopt envelope and twisted conformations, whereas the piperidine ring adopts an envelope conformation. The essentially planar 2,3-dihydroindanone unit [maximum deviation = −0.0163 (19) Å] is inclined at interplanar angles of 14.29 (9) and 61.07 (9)° to the two benzene rings. In the crystal, adjacent molecules are linked into dimers by intermolecular O—H...N and C—H...O hydrogen bonds. Short intermolecular Br...Br interactions [3.5140 (6) Å] further interconnect these dimers into double dimeric columns along the b axis.