Nanomaterials (Oct 2024)

Dynamics of Photoinduced Charge Carriers in Metal-Halide Perovskites

  • András Bojtor,
  • Dávid Krisztián,
  • Ferenc Korsós,
  • Sándor Kollarics,
  • Gábor Paráda,
  • Márton Kollár,
  • Endre Horváth,
  • Xavier Mettan,
  • Bence G. Márkus,
  • László Forró,
  • Ferenc Simon

DOI
https://doi.org/10.3390/nano14211742
Journal volume & issue
Vol. 14, no. 21
p. 1742

Abstract

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The measurement and description of the charge-carrier lifetime (τc) is crucial for the wide-ranging applications of lead-halide perovskites. We present time-resolved microwave-detected photoconductivity decay (TRMCD) measurements and a detailed analysis of the possible recombination mechanisms including trap-assisted, radiative, and Auger recombination. We prove that performing injection-dependent measurement is crucial in identifying the recombination mechanism. We present temperature and injection level dependent measurements in CsPbBr3, which is the most common inorganic lead-halide perovskite. In this material, we observe the dominance of charge-carrier trapping, which results in ultra-long charge-carrier lifetimes. Although charge trapping can limit the effectiveness of materials in photovoltaic applications, it also offers significant advantages for various alternative uses, including delayed and persistent photodetection, charge-trap memory, afterglow light-emitting diodes, quantum information storage, and photocatalytic activity.

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