Journal of Vasyl Stefanyk Precarpathian National University (May 2014)

SYNTHESIS AND PROPERTIES OF SUPERPARAMAGNETIC Y-Fe2O3

  • V.O. Kotsyubynsky,
  • V.V. Moklyak,
  • A.B. Hrubiak

DOI
https://doi.org/10.15330/jpnu.1.1.33-39
Journal volume & issue
Vol. 1, no. 1
pp. 33 – 39

Abstract

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Method of nanodispersed y-Fe2O3 synthesis by thermal decomposition of iron citrate is proposed. The investigations of obtained oxides crystal­line and magnetic structures are done. Nanodispersed y-Fe2O3 with sizes of coherent scattering regions about 4-7 nm was is only one phase after gel sintering at 200, 250 and 300оС; the particles of synthesized materials are in a state of magnetic ordering and in superparamagnetic state. The influence of mag­netic dipole interparticles interaction on parameters of Moss­bauer spectra is observed. The phenomenological mo­del of the differences between nanodispersed y-Fe2O3 magnetic micro­structures ob­tained after annealing at different tem­pe­ra­tu­res is presented.