Acta Crystallographica Section E (Oct 2012)

4-Acetyl-1H-pyrrole-2-carbaldehyde

  • Tao Sun,
  • Jia-Wei Xie,
  • Ren-Ying Zhao,
  • Ai-Guo Zhu,
  • Yan-Qing Ge

DOI
https://doi.org/10.1107/S1600536812039153
Journal volume & issue
Vol. 68, no. 10
pp. o2947 – o2947

Abstract

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The title compound, C7H7NO2, was synthesized via a one-pot Vilsmeier–Haack and subsequent Friedel–Crafts reaction. The pyrazole ring makes dihedral angles of 4.50 (9) and 2.06 (8)°, respectively, with the aldehyde and acetyl groups. In the crystal, classical N—H...O hydrogen bonds and weak C—H...O interactions assemble the molecules into a chain along the b axis.