Data for the synthesis of β-oxopropylcarbamates from propargylic alcohols, secondary amines and CO2 catalyzed by a recyclable AgBr/ionic liquid system under ambient pressure
Dandan Song,
Di Li,
Xuan Xiao,
Cheng Chen,
Somboon Chaemchuen,
Ye Yuan,
Francis Verpoort
Affiliations
Dandan Song
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, PR China; School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070, PR China
Di Li
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, PR China; School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070, PR China
Xuan Xiao
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, PR China; School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070, PR China
Cheng Chen
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, PR China
Somboon Chaemchuen
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, PR China
Ye Yuan
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, PR China; Corresponding author.
Francis Verpoort
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, PR China; School of Material Science and Engineering, Wuhan University of Technology, Wuhan 430070, PR China; National Research Tomsk Polytechnic University, Lenin Avenue 30, Tomsk 634050, Russian Federation; Global Campus Songdo, Ghent University, 119 Songdomunhwa-Ro, Yeonsu-Gu, Incheon, Republic of Korea; Corresponding author at: State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, PR China.
Data presented here are related with the research article entitled “Synthesis of ß -oxopropylcarbamates in a recyclable AgBr/ionic liquid catalytic system: An efficient assembly of CO2 under ambient pressure” (Song et al., 2018) [1]. In this data article, the general synthetic procedures of ß-oxopropylcarbamates through the three-component reaction of propargylic alcohols, secondary amines and carbon dioxide (CO2) catalyzed by a recyclable AgBr/ionic liquid (IL) system under mild pressure are described. Furthermore, the process for recycling the catalysts is supplied as well. Specifically, the investigative data for the temperature, amount of ILs, reaction time as well as the state of silver in the system are also reported. Finally, all the target products are confirmed by 1H NMR, 13C NMR, and high-resolution mass spectroscopy (HR-MS).
