Nanoparticle-Decorated Ultrathin La2O3 Nanosheets as an Efficient Electrocatalysis for Oxygen Evolution Reactions

Abstract

Abstract Electrochemical catalysts for oxygen evolution reaction are a critical component for many renewable energy applications. To improve their catalytic kinetics and mass activity are essential for sustainable industrial applications. Here, we report a rare-earth metal-based oxide electrocatalyst comprised of ultrathin amorphous La2O3 nanosheets hybridized with uniform La2O3 nanoparticles (La2O3@NP-NS). Significantly improved OER performance is observed from the nanosheets with a nanometer-scale thickness. The as-synthesized 2.27-nm La2O3@NP-NS exhibits excellent catalytic kinetics with an overpotential of 310 mV at 10 mA cm−2, a small Tafel slope of 43.1 mV dec−1, and electrochemical impedance of 38 Ω. More importantly, due to the ultrasmall thickness, its mass activity, and turnover frequency reach as high as 6666.7 A g−1 and 5.79 s−1, respectively, at an overpotential of 310 mV. Such a high mass activity is more than three orders of magnitude higher than benchmark OER electrocatalysts, such as IrO2 and RuO2. This work presents a sustainable approach toward the development of highly efficient electrocatalysts with largely reduced mass loading of precious elements.

Keywords

• Oxygen evolution reaction
• Multiphase hybrid
• Two-dimensional nanomaterials
• Rare-earth oxides
• Ionic layer epitaxy