BIOADSORVENTES DE RESÍDUOS DA AGROINDÚSTRIA UTILIZADOS NA REMOÇÃO DE Cd(II)

Abstract

The use of agroindustry waste in the synthesis of bioadsorbents provides a solution to reduce the disposal of solid waste in the environment while increasing the added value of recovering locally sourced waste. However, technical and environmental issues must be considered when selecting the appropriate synthesis method to avoid creating a new environmental impact and evaluate the feasibility of applying the method. In this work, yellow mombin, guava and mango seeds were used to synthesize bioadsorbents capable of removing cadmium(II) in solution. The materials were characterized according to their chemical composition, Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and evaluated by adsorption kinetics tests. Energy analysis of biomass processing was performed by life cycle analysis (LCA). The bioadsorbents presented typical characteristics of lignocellulosic biomass, with the presence of functional groups favorable to the adsorption of metals and were effective in removing cadmium(II), with efficiency of 95.7, 92.4 and 60.2%, for BSG (guava seed bioadsorbent), BSC (yellow mombin seed bioadsorbent) and BSM (mango seed bioadsorbent), respectively. The error functions provided a more appropriate criterion for analyzing the kinetic data. The methodology proposed in this work is simple to implement and has a low estimated energy demand, therefore being promising for application in small fruit processing industries in the semi-arid region of Bahia.