Optimized combustion temperature in the facile synthesis of Ni/Al2O3 catalyst for CO2 methanation

Abstract

Ni/Al2O3 catalysts (noted as Ni/Al-350, Ni/Al-500, and Ni/Al-700, respectively) were synthesized by a facile solution combustion method but at different combustion temperatures (350 °C, 500 °C, and 700 °C, respectively). For comparison, Ni/Al2O3 (noted as Ni/Al-100) was also prepared by the impregnation method and applied in the methanation reaction. The Ni/Al2O3 synthesized at the combustion temperature of 350 °C showed better performance than the others at higher combustion temperatures, and the activity for CO2 methanation followed an order of Ni/Al-350 > Ni/Al-500 > Ni/Al-700 > Ni/Al-100. The increase in the combustion temperature decreased active sites for the H2 and CO2 adsorption, which could be associated with the reduced Ni dispersion and basic sites, thus lowering its activity and increasing its carbon deposition rate.

Keywords

• CO2 methanation
• Nickel catalyst
• Facile method
• Solution combustion
• Carbon deposition
• Nickel agglomeration