Nature Communications (May 2016)

Synthesis of tetra- and octa-aurated heteroaryl complexes towards probing aromatic indoliums

  • Jun Yuan,
  • Tingting Sun,
  • Xin He,
  • Ke An,
  • Jun Zhu,
  • Liang Zhao

DOI
https://doi.org/10.1038/ncomms11489
Journal volume & issue
Vol. 7, no. 1
pp. 1 – 8

Abstract

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Polymetalated aromatic compounds are challenging synthetic goals. Here, the authors describe the synthesis of tetra-aurated indole and octa-aurated benzodipyrrole complexes, in which incorporation of the aurated substituents at the nitrogen atoms leads to hyperconjugative aromaticity in the five-membered rings.