Acta Crystallographica Section E (Jun 2010)

Tetraimidazolebis(trichloroacetato)copper(II)

  • Li-Min Li,
  • Huan-Mei Guo,
  • Fang-Fang Jian,
  • Zeng-Hui Zhang,
  • Ning Zhang

DOI
https://doi.org/10.1107/S1600536810017459
Journal volume & issue
Vol. 66, no. 6
pp. m682 – m682

Abstract

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The title compound, [Cu(C2Cl3O2)2(C3H4N2)4], was prepared by the reaction of imidazole and trichloroacetatocopper(II). The CuII atom adopts a distorted octahedral coordination geometry, binding the N atoms of four imidazole ligands and the carboxylate O atoms of two trichloroacetate anions. The molecular structure and packing are stabilized by N—H...O hydrogen-bonding interactions. Close intermolecular Cl...Cl contacts [3.498 (3) Å] are also found in the structure.