Results in Materials (Dec 2024)
Impact of PECVD deposition on dielectric charge and passivation for n-GaN/SiOx interfaces
Abstract
Controlling properties of GaN/dielectric interfaces is crucial for determining the characteristics of MOS-HEMT devices and their stability. Interface properties are largely affected by the techniques and specific conditions of dielectric deposition. In this work, a Taguchi design of experiment was applied to study the effect of plasma parameters during deposition of SiOx by PECVD for passivation of n-GaN. SiOx/GaN MIS capacitors were fabricated and characterized by capacitance measurement at a high probing frequency of 1 MHz. The interface states density, hysteresis and flatband voltage were analyzed and modeled in relation with the flow of SiH4, plasma power, chamber pressure and temperature. Excellent fits could be obtained on a single model including linear terms for all studied parameters and quadratic terms for the flow of SiH4 and temperature. We show that it is possible to obtain some control of the flatband voltage while maintaining a good interface quality. Positive flatband voltages are potentially of interest to enable normally-off operation for MOS-HEMTs and this could be obtained mainly by using a high SiH4/N2O ratio. To the contrary, negative flatband voltage values often ensure the most stable operation of MOS-HEMTs and this was achieved with a low SiH4/N2O and high plasma power. MIS capacitors with near-zero flatband voltage were also obtained with low SiH4/N2O ratio and low plasma power. Hysteresis and interface states density in relation with deposition plasma conditions are also analyzed in order to offer the best trade-offs depending on the end applications of MOS-GaN devices. By demonstrating the great impact of plasma conditions during dielectric deposition on electronic properties of MIS devices, we show that the process of gate insulation can be optimized to simultaneously control the density of defects and fixed charge at the interface.
