Protective Spinel Coating for Li<sub>1.17</sub>Ni<sub>0.17</sub>Mn<sub>0.50</sub>Co<sub>0.17</sub>O<sub>2</sub> Cathode for Li-Ion Batteries through Single-Source Precursor Approach
Andrey Shevtsov,
Haixiang Han,
Anatolii Morozov,
Jesse C. Carozza,
Aleksandra A. Savina,
Iaroslava Shakhova,
Nellie R. Khasanova,
Evgeny V. Antipov,
Evgeny V. Dikarev,
Artem M. Abakumov
Affiliations
Andrey Shevtsov
Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Nobel str. 3, 143026 Moscow, Russia
Haixiang Han
Department of Chemistry, University at Albany, Albany, NY 12222, USA
Anatolii Morozov
Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Nobel str. 3, 143026 Moscow, Russia
Jesse C. Carozza
Department of Chemistry, University at Albany, Albany, NY 12222, USA
Aleksandra A. Savina
Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Nobel str. 3, 143026 Moscow, Russia
Iaroslava Shakhova
Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Nobel str. 3, 143026 Moscow, Russia
Nellie R. Khasanova
Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia
Evgeny V. Antipov
Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Nobel str. 3, 143026 Moscow, Russia
Evgeny V. Dikarev
Department of Chemistry, University at Albany, Albany, NY 12222, USA
Artem M. Abakumov
Center for Energy Science and Technology, Skolkovo Institute of Science and Technology, Nobel str. 3, 143026 Moscow, Russia
The Li1.17Ni0.17Mn0.50Co0.17O2 Li-rich NMC positive electrode (cathode) for lithium-ion batteries has been coated with nanocrystals of the LiMn1.5Co0.5O4 high-voltage spinel cathode material. The coating was applied through a single-source precursor approach by a deposition of the molecular precursor LiMn1.5Co0.5(thd)5 (thd = 2,2,6,6-tetramethyl-3,5-heptanedionate) dissolved in diethyl ether, followed by thermal decomposition at 400 °C inair resulting in a chemically homogeneous cubic spinel. The structure and chemical composition of the coatings, deposited on the model SiO2 spheres and Li-rich NMC crystallites, were analyzed using powder X-ray diffraction, electron diffraction, high angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), and energy-dispersive X-ray (EDX) mapping. The coated material containing 12 wt.% of spinel demonstrates a significantly improved first cycle Coulombic efficiency of 92% with a high first cycle discharge capacity of 290 mAhg−1. The coating also improves the capacity and voltage retention monitored over 25 galvanostatic charge–discharge cycles, although a complete suppression of the capacity and voltage fade is not achieved.
