Thermodynamic Assessment and Solubility of Ni in LBE Coolants

Abstract

Lead–Bismuth Eutectic (LBE) is a heavy metal liquid alloy used as a coolant for compact high temperature reactors (CHTRs), fast breeder reactor (FBRs) and as a spallation target for ADS. In spite of many advantages due to its thermophysical properties, corrosion towards structural materials remains one of the major issues of LBE. In absence of any oxygen impurity, corrosion in LBE is driven by dissolution processes and the solubility of the main elements of the structural material alloys. Using the CALPHAD method, Thermo-Calc software, a thermodynamic database was developed to assess the interaction between Ni and LBE coolant. The solubilities of Ni in LBE, Bi and Pb liquids have been calculated at different temperatures.

Keywords

• LBE
• Thermo-Calc
• solubility
• CALPHAD