Defect Modes Generated in a Stack of Spin-Coated Chiral Liquid Crystal Layers

Abstract

Nematic chiral liquid crystals (CLCs) are characterized by a helical arrangement of nematic LC molecules. A layer of CLC typically exhibits an optical reflection band due to Bragg reflection in the helical structure. When several layers of CLC are spin-coated and polymerized on top of each other without a barrier layer in between, defect modes can form in their reflection spectrum. By comparing experimental results and simulations, we investigate the origin of the defect modes, thereby revealing details on the behavior of the materials at the interfaces during deposition. Simulations show that these defect modes can originate from the migration of chiral dopant leading to a layer with a smaller pitch or from a discontinuity in the director orientation at the interface between two layers.

Keywords

• CLC
• PCLC
• polymerized chiral liquid crystal
• defect modes
• diffusion
• blue shift