To Chemistry Journal (Dec 2018)
Effect of Oxidant 1, 3-Dichloro-5-5-Dimethylhydantoin and 5, 5-Dimethylhydantoin with Different Substrates: The Kinetic Measurements
Abstract
The kinetic measurement with different concentration of oxidant 1,3-dichloro-5,5-dimethylhydantoin and 5,5-dimethylhydantoin with ℓ–alanine, ℓ-glycine and ℓ–valine. The catalytic effect of acid in the reaction rate reveal an interaction between oxidants species H2O+Cl and substrates. The observed order of reactivity of ℓ-amino acids (ℓ-glycine > ℓ–alanine > ℓ-valine) was explained on the basis of hydrolysis of reacting species.