Modeling of Isocyanate Synthesis by the Thermal Decomposition of Carbamates
Ratmir Dashkin,
Georgii Kolesnikov,
Pavel Tsygankov,
Igor Lebedev,
Artem Lebedev,
Natalia Menshutina,
Khusrav Ghafurov,
Abakar Bagomedov
Affiliations
Ratmir Dashkin
Engineering Center, Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russia
Georgii Kolesnikov
Engineering Center, Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russia
Pavel Tsygankov
International Science and Education Center for Transfer of Biopharmaceutical Technologies, Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russia
Igor Lebedev
International Science and Education Center for Transfer of Biopharmaceutical Technologies, Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russia
Artem Lebedev
International Science and Education Center for Transfer of Biopharmaceutical Technologies, Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russia
Natalia Menshutina
International Science and Education Center for Transfer of Biopharmaceutical Technologies, Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russia
Khusrav Ghafurov
Engineering Center, Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russia
Abakar Bagomedov
Engineering Center, Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russia
The presented work is devoted to isocyanate synthesis by the thermal decomposition of carbamates model. The work describes the existing isocyanate-obtaining processes and the main problems in the study of isocyanate synthesis by the thermal decomposition of carbamates, which can be solved using mathematical and computer models. Experiments with carbamates of various structures were carried out. After processing the experimental data, the activation energy and the pre-exponential factor for isocyanate synthesis by the thermal decomposition of carbamates were determined. Then, a mathematical model of the reactor for the thermal decomposition of carbamates using the COMSOL Multiphysics software was developed. For this model, computational experiments under different conditions were carried out. It was shown that the calculation results correspond to the experimental ones, so the suggested model can be used in the design of the equipment for isocyanate synthesis by the thermal decomposition of carbamates.
