Analysis of Mercury in Aquifers in Gold Mining Areas in the Ecuadorian Amazon and Its Associated Risk for Human Health
Irene Passarelli,
Michelle Vanessa Villacis Verdesoto,
Samantha Jiménez-Oyola,
Ana Gabriela Flores Huilcapi,
Demmy Mora-Silva,
Giorgio Anfuso,
Jose Fernando Esparza Parra,
Mirian Jimenez-Gutierrez,
Luis Santiago Carrera Almendáriz,
Victor Gabriel Avalos Peñafiel,
Salvatore Straface,
Carlos Mestanza-Ramón
Affiliations
Irene Passarelli
Department of Environmental Engineering, University of Calabria, 87036 Rende, Italy
Michelle Vanessa Villacis Verdesoto
Green Amazon, Research Center, Nueva Loja 210150, Ecuador
Samantha Jiménez-Oyola
Escuela Superior Politécnica del Litoral, ESPOL, Facultad de Ingeniería en Ciencias de la Tierra, ESPOL Polytechnic University, Campus Gustavo Galindo km 30.5 Vía Perimetral, P.O. Box 09-01-5863, Guayaquil 090101, Ecuador
Ana Gabriela Flores Huilcapi
Faculty of Food Science and Engineering and Biotechnology, Universidad Técnica de Ambato, Av. Colombia y Chile, Ambato 180104, Ecuador
Demmy Mora-Silva
Research Group YASUNI-SDC, Escuela Superior Politécnica de Chimborazo, Sede Orellana, El Coca 220001, Ecuador
Giorgio Anfuso
Department of Earth Sciences, Faculty of Marine and Environmental Sciences, University of Cádiz, 11510 Puerto Real, Spain
Jose Fernando Esparza Parra
Escuela Superior Politécnica de Chimborazo (ESPOCH), Faculty of Natural Resources, Panamericana Sur km 1 ½, Riobamba 060155, Ecuador
Mirian Jimenez-Gutierrez
Green Amazon, Research Center, Nueva Loja 210150, Ecuador
Luis Santiago Carrera Almendáriz
Green Amazon, Research Center, Nueva Loja 210150, Ecuador
Victor Gabriel Avalos Peñafiel
Green Amazon, Research Center, Nueva Loja 210150, Ecuador
Salvatore Straface
Department of Environmental Engineering, University of Calabria, 87036 Rende, Italy
Carlos Mestanza-Ramón
Department of Environmental Engineering, University of Calabria, 87036 Rende, Italy
Gold mining activity is a source of supply in many areas of the world, and especially in developing countries, it is practiced illegally and by applying unsafe techniques. Particularly in Ecuador, artisanal and small-scale gold mining (ASGM) is widespread, and it is based on the use of toxic substances, such as mercury (Hg), in gold recovery. Hg is a heavy metal that is water-insoluble, which, once mobilized, poses a threat to both the environment and human health. This study analyzes Hg concentrations in the six provinces of Napo, Sucumbíos, Orellana, Pastaza, Morona Santiago, and Zamora Chinchipe of the Ecuadorian Amazon region to conduct a human health risk assessment. Significant differences in Hg levels were found between provinces, but concentrations were below MPL imposed by Ecuadorian regulations everywhere. Nevertheless, a worrisome picture emerges, especially with regard to the most vulnerable receptors represented by the child population. There are multiple factors of incidence that may affect the possible future development of the phenomenon, and with reference to the social, economic, and environmental context of the region, it can be concluded that it may be appropriate to plan further investigation to arrive at a more comprehensive assessment. The results of this study can be used by decision makers to plan further investigation and to implement monitoring networks, risk mitigation strategies, and groundwater protection measures.