Solid Electrolyte Interphase Growth in Lithium Metal Cells With Normal Electrolyte Flow

Abstract

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In high energy density lithium metal batteries (LMBs), dendrite and solid electrolyte interphase (SEI) growth reduce safety and longevity, respectively. A stable SEI layer enables high efficiency cycling but continued SEI growth can lead to reduced capacity and coulombic efficiency. In this paper, we develop a steady-state model that predicts the effect of small advective electrolyte flow towards the lithium metal electrode on SEI growth during charging. For a fixed current density, increasing the electrolyte flow rate improves the coulombic efficiency and decreases SEI layer growth rate. Decreasing the charging current density at a constant flow rate also decreases the SEI layer growth rate. Low flow rates (μm/s) can increase coulombic efficiency by up to 6%. The sensitivity of the coulombic efficiency to plating and SEI layer reaction rates is also explored.

Keywords

• solid electrolyte interphase
• lithium metal cells
• normal electrolyte flow
• coulombic efficiency
• dendrite