EPJ Web of Conferences (Jan 2016)
Complex chemistry with complex compounds
- Eichler Robert,
- Asai M.,
- Brand H.,
- Chiera N.M.,
- Di Nitto A.,
- Dressler R.,
- Düllmann Ch.E.,
- Even J.,
- Fangli F.,
- Goetz M.,
- Haba H.,
- Hartmann W.,
- Jäger E.,
- Kaji D.,
- Kanaya J.,
- Kaneya Y.,
- Khuyagbaatar J.,
- Kindler B.,
- Komori Y.,
- Kraus B.,
- Kratz J.V.,
- Krier J.,
- Kudou Y.,
- Kurz N.,
- Miyashita S.,
- Morimoto K.,
- Morita K.,
- Murakami M.,
- Nagame Y.,
- Ooe K.,
- Piguet D.,
- Sato N.,
- Sato T.K.,
- Steiner J.,
- Steinegger P.,
- Sumita T.,
- Takeyama M.,
- Tanaka K.,
- Tomitsuka T.,
- Toyoshima A.,
- Tsukada K.,
- Türler A.,
- Usoltsev I.,
- Wakabayashi Y.,
- Wang Y.,
- Wiehl N.,
- Wittwer Y.,
- Yakushev A.,
- Yamaki S.,
- Yano S.,
- Yamaki S.,
- Qin Z.
Affiliations
- Eichler Robert
- Asai M.
- Advanced Science Research Center, Japan Atomic Energy Agency
- Brand H.
- GSI Helmholtzzentrum für Schwerionenforschung GmbH
- Chiera N.M.
- Di Nitto A.
- Dressler R.
- Paul Scherrer Institute
- Düllmann Ch.E.
- Even J.
- Fangli F.
- Institute of Modern Physics Lanzhou, Chinese Academy of Sciences
- Goetz M.
- Haba H.
- Nishina Center for Accelerator-Based Science, RIKEN
- Hartmann W.
- GSI Helmholtzzentrum für Schwerionenforschung GmbH
- Jäger E.
- GSI Helmholtzzentrum für Schwerionenforschung GmbH
- Kaji D.
- Nishina Center for Accelerator-Based Science, RIKEN
- Kanaya J.
- Nishina Center for Accelerator-Based Science, RIKEN
- Kaneya Y.
- Advanced Science Research Center, Japan Atomic Energy Agency
- Khuyagbaatar J.
- Kindler B.
- GSI Helmholtzzentrum für Schwerionenforschung GmbH
- Komori Y.
- Nishina Center for Accelerator-Based Science, RIKEN
- Kraus B.
- Kratz J.V.
- Johannes Gutenberg-Universität Mainz
- Krier J.
- GSI Helmholtzzentrum für Schwerionenforschung GmbH
- Kudou Y.
- Nishina Center for Accelerator-Based Science, RIKEN
- Kurz N.
- GSI Helmholtzzentrum für Schwerionenforschung GmbH
- Miyashita S.
- Morimoto K.
- Nishina Center for Accelerator-Based Science, RIKEN
- Morita K.
- Murakami M.
- Nagame Y.
- Advanced Science Research Center, Japan Atomic Energy Agency
- Ooe K.
- Niigata University
- Piguet D.
- Paul Scherrer Institute
- Sato N.
- Nishina Center for Accelerator-Based Science, RIKEN
- Sato T.K.
- Advanced Science Research Center, Japan Atomic Energy Agency
- Steiner J.
- GSI Helmholtzzentrum für Schwerionenforschung GmbH
- Steinegger P.
- Sumita T.
- Nishina Center for Accelerator-Based Science, RIKEN
- Takeyama M.
- Nishina Center for Accelerator-Based Science, RIKEN
- Tanaka K.
- Nishina Center for Accelerator-Based Science, RIKEN
- Tomitsuka T.
- Niigata University
- Toyoshima A.
- Advanced Science Research Center, Japan Atomic Energy Agency
- Tsukada K.
- Advanced Science Research Center, Japan Atomic Energy Agency
- Türler A.
- Usoltsev I.
- Wakabayashi Y.
- Nishina Center for Accelerator-Based Science, RIKEN
- Wang Y.
- Institute of Modern Physics Lanzhou, Chinese Academy of Sciences
- Wiehl N.
- Wittwer Y.
- Yakushev A.
- Yamaki S.
- Nishina Center for Accelerator-Based Science, RIKEN
- Yano S.
- Nishina Center for Accelerator-Based Science, RIKEN
- Yamaki S.
- Nishina Center for Accelerator-Based Science, RIKEN
- Qin Z.
- Institute of Modern Physics Lanzhou, Chinese Academy of Sciences
- DOI
- https://doi.org/10.1051/epjconf/201613107005
- Journal volume & issue
-
Vol. 131
p. 07005
Abstract
In recent years gas-phase chemical studies assisted by physical pre-separation allowed for the investigation of fragile single molecular species by gas-phase chromatography. The latest success with the heaviest group 6 transactinide seaborgium is highlighted. The formation of a very volatile hexacarbonyl compound Sg(CO)6 was observed similarly to its lighter homologues molybdenum and tungsten. The interactions of these gaseous carbonyl complex compounds with quartz surfaces were investigated by thermochromatography. Second-generation experiments are under way to investigate the intramolecular bond between the central metal atom of the complexes and the ligands addressing the influence of relativistic effects in the heaviest compounds. Our contribution comprises some aspects of the ongoing challenging experiments as well as an outlook towards other interesting compounds related to volatile complex compounds in the gas phase.
