Photocatalytic Efficacy of Heterocyclic Base Grafted Chitosan Magnetite Nanoparticles on Sorption of Pb(II); Application on Mining Effluent

Abstract

Development of bio-based sorbents (i.e., chitosan moieties) at nanoscale size for the removal of metal contaminants is the main target of this research. Grafting with thiazole heterocyclic derivative gives fast kinetics sorption, highly metal loading, and good recyclability for mining leaching solution. Different analyses tools including (thermogravimetric analysis (TGA), scanning electron microscope and energy dispersive spectroscopy (SEM-EDX), X-ray diffraction (XRD), Fourier transform infrared (FTIR), BET surface area (nitrogen sorption desorption), titration, and TEM (transmission electron microscopy)) were used to investigate the chemical and textural properties of the functionalized sorbent. The sorption was measured in normal visible light and under UV emission. The highest capacity was measured at pH 5, which reached 0.251 mmol Pb g−1 in visible light compared with 0.346 mmol Pb g−1 under UV for the pristine crosslinked chitosan (MCc). The sorption performances were improved by functionalization; (0.7814 and 1.014 mmol Pb g−1) for the functionalized sorbent (MCa-ATA) under visible light and UV, respectively. PFORE (pseudo-first-order rate equation) and RIDE (resistance to intraparticle diffusion) fit kinetics, the Sips equation is the most fit profile for the sorption isotherms for the MCc in either light and UV processes, while PFORE and RIDE for kinetics under light and UV for MCa-ATA and Sips in light and Sips and Langmuir under the UV emission. Finally, the sorbent was investigated toward a raffinate solution from ore processing and shows promising extraction tools for the most interesting elements.

Keywords

• photocatalysis
• bio-based materials
• metal-contamination
• nanoscale particles