Characterization of Thermoplastic Starch Plasticized with Ternary Urea-Polyols Deep Eutectic Solvent with Two Selected Fillers: Microcrystalline Cellulose and Montmorillonite

Abstract

The aim of the study was to prepare and characterize composite materials based on thermoplastic starch (TPS)/deep eutectic solvent (DES). Potato starch was plasticized with ternary DES: urea:glycerol:sorbitol and modified with the selected fillers: microcrystalline cellulose and sodium montmorillonite. Films were prepared via twin-screw extrusion and thermocompression of the extrudates. Then, the physicochemical properties of the TPS films were examined. The ternary DES effectively plasticized the polysaccharide leading to a highly amorphous structure of the TPS (confirmed via mechanical tests, DMTA and XRD analyses). An investigation of the behavior in water (swelling and dissolution degree) and water vapor transmission rate of the films was determined. The introduction of the two types of fillers resulted in higher tensile strength and better barrier properties of the composite TPS films. However, montmorillonite addition exhibited a higher impact than microcrystalline cellulose. Moreover, a cone calorimetry analysis of the TPS materials revealed that they showed better fire-retardant properties than TPS plasticized with a conventional plasticizer (glycerol).

Keywords

• cone calorimetry
• deep eutectic solvents
• fillers
• fire behavior
• microcrystalline cellulose
• montmorillonite