Rheological properties of carboxymethyl cellulose (CMC) solution: Impact of high intensity ultrasound

Abstract

Today sonication process is used as a new green tool with unique impacts on foods preservation and processing. Ultrasonic modification is an appropriate strategy to obtain good gums with useful physicochemical characteristics and molecular structure. This research aimed to analyze the impacts of sonication at different intensities (0, 75, and 150 W) and time (0, 5, 10, 15, and 20 min) on the viscosity and rheological characteristics of carboxymethyl cellulose (CMC) solution. The results confirmed that the apparent viscosity of CMC solution reduced from 0.030 to 0.021 Pa.s with increasing shear-rate from 12.2 s−1 to 134.5 s−1 (75 W for 10 min). Also, the apparent viscosity of CMC solution reduced from 0.028 to 0.019 Pa.s with enhancing the sonication time from 0 to 20 min (shear-rate = 61 s−1, 150 W). Various rheological equations were employed to fit the empirical values, and the results confirmed that the Power law model was the best fit to explain the flow behaviour of CMC solution. The consistency coefficient of CMC solution significantly reduced from 0.065 Pa.sn to 0.032 Pa.sn (p < 0.05) with enhancing sonication time from 0 to 20 min (75 W). Furthermore, the consistency coefficient of CMC solution decreased significantly (p < 0.05) while the ultrasonic power enhanced. Flow behaviour index of CMC solution enhanced significantly (p < 0.05) while the intensity and time of sonication enhanced.

Keywords

• Apparent viscosity
• Carboxymethyl cellulose
• Consistency coefficient
• Flow behaviour index
• Rheological models
• Ultrasound