Acta Crystallographica Section E (Jul 2009)

{Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ3P,P′,P′′}chloridoplatinium(II) hexafluoridophosphate

  • Scott A. Heston,
  • Bruce C. Noll,
  • Monte L. Helm

DOI
https://doi.org/10.1107/S1600536809022405
Journal volume & issue
Vol. 65, no. 7
pp. m793 – m793

Abstract

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In the title compound, [PtCl(C34H33P3)]PF6, the PtII cation adopts a distorted square-planar PtClP3 geometry, arising from the P,P′,P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF6− anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio.