Nanocarbon hybrid for simultaneous removal of arsenic, iron and manganese ions from aqueous solutions

Abstract

Heavy metal contamination is a severe problem with serious ecological and human health effects due to its toxic effect and tendency to accumulate throughout the food chain. Batch experiments were conducted to investigate the simultaneous removal of arsenic, iron and manganese ions from aqueous solutions using Nanocarbon hybrid (NCH). Nanocarbon hybrid (NCH) of carbon xerogel decorated with 1wt% multi-walled carbon nanotubes was prepared by carbonization at 850 °C for 2 h. The TEM, SEM, EDX, FTIR, and N2 adsorption-desorption measurements were used to characterize the prepared NCH. NCH is enriched with surface oxygen functional groups and micropores as well as it have total surface area of 162 m2/g and total pore volume of 0.129 cm3/g. The adsorption of metal ions onto NCH, which confirmed by EDX, happened quickly, with 30%, 97%, and 41% of As, Fe, and Mn adsorbed in less than 10 min, however the equilibrium time was achieved in less than 30 min. The maximum adsorption capacities for As, Fe, and Mn ions onto NCH were 20, 48, and 21 mg/g, respectively. The experimental adsorption results of the three metal ions showed linearly fitting with Freundlich isotherms. In addition, the computed adsorption energies for Fe, Mn, and As ions were 4.08, 1.95, and 2.42 kJ/mol, indicating physical adsorption. NCH are easily regenerated and reusable sorbent owing to the adsorption–desorption studies. Conclusively, NCH is promising material for removing mixture of metal ions from aqueous media.

Keywords

• Nanocarbon hybrid
• As
• Fe
• Mn
• Adsorption
• Isotherm