Per- and polyfluoralkyl substances (PFAS) in drinking water system: Target and non-target screening and removal assessment

Yu-Qing Wang; Li-Xin Hu; Ting Liu; Jia-Hui Zhao; Yuan-Yuan Yang; You-Sheng Liu; Guang-Guo Ying

Environment International (May 2022)

Per- and polyfluoralkyl substances (PFAS) in drinking water system: Target and non-target screening and removal assessment

Yu-Qing Wang,
Li-Xin Hu,
Ting Liu,
Jia-Hui Zhao,
Yuan-Yuan Yang,
You-Sheng Liu,
Guang-Guo Ying

Affiliations

Yu-Qing Wang: SCNU Environmental Research Institute, Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety & MOE Key Laboratory of Theoretical Chemistry of Environment, South China Normal University, Guangzhou 510006, China; School of Environment, South China Normal University, University Town, Guangzhou 510006, China
Li-Xin Hu: Corresponding authors at: School of Environment, South China Normal University, University Town, Guangzhou 510006, China.; SCNU Environmental Research Institute, Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety & MOE Key Laboratory of Theoretical Chemistry of Environment, South China Normal University, Guangzhou 510006, China; School of Environment, South China Normal University, University Town, Guangzhou 510006, China
Ting Liu: SCNU Environmental Research Institute, Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety & MOE Key Laboratory of Theoretical Chemistry of Environment, South China Normal University, Guangzhou 510006, China; School of Environment, South China Normal University, University Town, Guangzhou 510006, China
Jia-Hui Zhao: SCNU Environmental Research Institute, Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety & MOE Key Laboratory of Theoretical Chemistry of Environment, South China Normal University, Guangzhou 510006, China; School of Environment, South China Normal University, University Town, Guangzhou 510006, China
Yuan-Yuan Yang: SCNU Environmental Research Institute, Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety & MOE Key Laboratory of Theoretical Chemistry of Environment, South China Normal University, Guangzhou 510006, China; School of Environment, South China Normal University, University Town, Guangzhou 510006, China
You-Sheng Liu: SCNU Environmental Research Institute, Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety & MOE Key Laboratory of Theoretical Chemistry of Environment, South China Normal University, Guangzhou 510006, China; School of Environment, South China Normal University, University Town, Guangzhou 510006, China
Guang-Guo Ying: Corresponding authors at: School of Environment, South China Normal University, University Town, Guangzhou 510006, China.; SCNU Environmental Research Institute, Guangdong Provincial Key Laboratory of Chemical Pollution and Environmental Safety & MOE Key Laboratory of Theoretical Chemistry of Environment, South China Normal University, Guangzhou 510006, China; School of Environment, South China Normal University, University Town, Guangzhou 510006, China

Journal volume & issue: Vol. 163
p. 107219

Abstract

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The massive use and the persistence of per- and polyfluoroalkyl substances (PFAS) have led to their frequent detection in aquatic environments, which may further threaten drinking water safety. So far, our knowledge about the occurrence of PFAS in drinking water system is still very limited. Here we investigated the occurrence and removal of PFAS in a drinking water system using non-target, suspect and target screening strategies. Sampling was performed in three seasons in the drinking water system including a water source, two drinking water treatment plants, and tap water in five households. The results showed detection of 17 homologous series with 51 homologues in non-target screening and 50 potential PFAS detected in suspect screening. Probable structures were proposed for 15 PFAS with high confidence levels (the first three of the five levels), with seven of them being reported for the first time in drinking water system. Semi-quantification was performed on seven homologous series based on target PFAS, the estimated total concentrations for non-target PFAS ranged between 4.10 and 17.6 ng/L. Nine out of 50 target PFAS were found and precisely quantified (<LOQ-13.4 ng/L) with predominance of perfluorocarboxylic acids (PFCA) and perfluorosulfonic acids (PFSA). All target and non-target PFAS were detected in tap water with similar concentrations in all three seasons. Removal efficiency for the detected PFAS in each processing unit was almost zero, indicating the recalcitrance of these chemicals to the conventional treatment process. The findings from this study clearly show the wide presence of PFAS in the whole drinking water treatment process, and suggest an urgent need for effective removal technology for this group of chemicals.

Published in Environment International

ISSN: 0160-4120 (Print)
Publisher: Elsevier
Country of publisher: United Kingdom
LCC subjects: Geography. Anthropology. Recreation: Environmental sciences
Website: https://www.journals.elsevier.com/environment-international

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